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The origin of the Hartree—Fock method dates back to the end of the s, soon after the discovery of the Schrödinger equation in Douglas Hartree's methods were guided by some earlier, semi-empirical methods of the early s by E.

Fues, R. Lindsay , and himself set in the old quantum theory of Bohr. It was observed from atomic spectra that the energy levels of many-electron atoms are well described by applying a modified version of Bohr's formula.

The existence of a non-zero quantum defect was attributed to electron—electron repulsion, which clearly does not exist in the isolated hydrogen atom.

This repulsion resulted in partial screening of the bare nuclear charge. These early researchers later introduced other potentials containing additional empirical parameters with the hope of better reproducing the experimental data.

In , D. Hartree introduced a procedure, which he called the self-consistent field method, to calculate approximate wave functions and energies for atoms and ions.

His first proposed method of solution became known as the Hartree method , or Hartree product. However, many of Hartree's contemporaries did not understand the physical reasoning behind the Hartree method: it appeared to many people to contain empirical elements, and its connection to the solution of the many-body Schrödinger equation was unclear.

However, in J. Slater and J. Gaunt independently showed that the Hartree method could be couched on a sounder theoretical basis by applying the variational principle to an ansatz trial wave function as a product of single-particle functions.

In , Slater and V. Fock independently pointed out that the Hartree method did not respect the principle of antisymmetry of the wave function.

However, this was shown to be fundamentally incomplete in its neglect of quantum statistics. A solution to the lack of anti-symmetry in the Hartree method came when it was shown that a Slater determinant , a determinant of one-particle orbitals first used by Heisenberg and Dirac in , trivially satisfies the antisymmetric property of the exact solution and hence is a suitable ansatz for applying the variational principle.

The original Hartree method can then be viewed as an approximation to the Hartree—Fock method by neglecting exchange. Fock's original method relied heavily on group theory and was too abstract for contemporary physicists to understand and implement.

In , Hartree reformulated the method to be more suitable for the purposes of calculation. The Hartree—Fock method, despite its physically more accurate picture, was little used until the advent of electronic computers in the s due to the much greater computational demands over the early Hartree method and empirical models.

Initially, both the Hartree method and the Hartree—Fock method were applied exclusively to atoms, where the spherical symmetry of the system allowed one to greatly simplify the problem.

These approximate methods were and are often used together with the central field approximation , to impose the condition that electrons in the same shell have the same radial part, and to restrict the variational solution to be a spin eigenfunction.

Even so, calculating a solution by hand using the Hartree—Fock equations for a medium-sized atom was laborious; small molecules required computational resources far beyond what was available before The Hartree—Fock method is typically used to solve the time-independent Schrödinger equation for a multi-electron atom or molecule as described in the Born—Oppenheimer approximation.

Since there are no known analytic solutions for many-electron systems there are solutions for one-electron systems such as hydrogenic atoms and the diatomic hydrogen cation , the problem is solved numerically.

Due to the nonlinearities introduced by the Hartree—Fock approximation, the equations are solved using a nonlinear method such as iteration , which gives rise to the name "self-consistent field method".

Relaxation of the last two approximations give rise to many so-called post-Hartree—Fock methods. The variational theorem states that for a time-independent Hamiltonian operator, any trial wave function will have an energy expectation value that is greater than or equal to the true ground-state wave function corresponding to the given Hamiltonian.

Because of this, the Hartree—Fock energy is an upper bound to the true ground-state energy of a given molecule. In the context of the Hartree—Fock method, the best possible solution is at the Hartree—Fock limit ; i.

The other is the full-CI limit , where the last two approximations of the Hartree—Fock theory as described above are completely undone. It is only when both limits are attained that the exact solution, up to the Born—Oppenheimer approximation, is obtained.

The Hartree—Fock energy is the minimal energy for a single Slater determinant. The starting point for the Hartree—Fock method is a set of approximate one-electron wave functions known as spin-orbitals.

For an atomic orbital calculation, these are typically the orbitals for a hydrogen-like atom an atom with only one electron, but the appropriate nuclear charge.

For a molecular orbital or crystalline calculation, the initial approximate one-electron wave functions are typically a linear combination of atomic orbitals LCAO.

The orbitals above only account for the presence of other electrons in an average manner. They split shortly afterward; Zenk claimed Martel had secretly negotiated an individual contract worth three times more than his partner's contract traditionally, tag teams are paid roughly equal salaries.

Martel strongly disagreed. I did the same thing with Tom, and he put it in his head, or some other people put it in his head, that I made more than him.

But as far as Vince was concerned, if you were in a tag team, you earned the same amount of money. Wrestling is very hard on your body.

Hard on you also mentally. It's hard physically. Tom wasn't mentally or physically hard as I thought he would be. At the time of Zenk's departure, The Can-Am Connection was in a feud with The Islanders Haku and Tama ; Zenk's departure was worked into the feud, with the Islanders claiming that Zenk was a quitter and abandoned Martel because he knew they could never beat them.

In July , Martel defeated both Haku and Tama in singles competition. Tito Santana , who was doing commentary in the Spanish broadcast booth, ran to the ring to help Martel fight off his attackers.

Martel and Santana then formed a tag team called Strike Force. The team were played off as good looking pretty boys a storyline that came directly from the Can-Am Connection , even using the theme called "Girls In Cars", which was originally made for the Can-Am Connection.

The name Strike Force came from Santana's promise that as a team they would, "be striking The Islanders with force.

Strike Force won the titles on an episode of Superstars after Martel made Neidhart submit to a Boston crab. Fuji 's cane as a weapon when Martel had Smash in the Boston crab and the referee was distracted by Santana beating up Mr.

Fuji on the ring apron. Shortly afterward, Martel kayfabe took time off due to injuries sustained in a title rematch against Demolition at a Prime Time Wrestling taping in Oakland , California on June 1, aired July Smash hit Martel with a steel chair, then Demolition performed their "Demolition Decapitation" finisher on him at ringside, leaving him unconscious on the floor.

On the June 18 Superstars , it was announced he suffered back injuries and a concussion. In the storyline, he briefly retired due to these injuries.

In reality, he was granted leave from the WWF and took six months off to help care for his severely ill wife. During the match, Santana accidentally hit Martel with his signature flying forearm smash and knocked him out of the ring.

A frustrated Martel refused to tag in and walked away, leaving Santana to be beaten down and pinned. I'm sick and tired of him.

You know, I was doing great as a singles wrestler, but no, Mr. Tito wants to ride my coattails some more.

You saw his timing was off". Then angrily addressing Santana he said "You're lucky that being the gentleman that I am that I just walked off.

That could have been a lot worse for you Tito Santana. Following his heel turn , Martel acquired Slick as his manager.

He feuded with Santana on and off over the next two years, losing to him in the finals of the King of the Ring tournament , then defeating him at The Main Event IV taping on October 30, aired November In late , Martel adopted a narcissistic gimmick, as the Model.

Just before the Survivor Series where in a continuation of their feud, Martel pinned Santana in the opening elimination match of the night , he introduced his own fictional brand of cologne called Arrogance , which he carried in a large atomizer and sprayed in the eyes of his opponents to blind them.

He wore a turquoise sweater tied around his neck to the ring later replaced by a turquoise sportcoat , with a large lapel pin that read "Yes, I am a model.

Ware via submission with his signature Boston Crab. Martel and Roberts captained opposing teams at the Survivor Series.

How Much Have You Seen? How much of Markus Knüfken's work have you seen? Gender Swap! Classic male characters to be played by a woman?

Known For. Knockin' on Heaven's Door 1. Millennium Mann Nicholas Beyer. Auf Achse Eddi. Maja Marc. Jump to: Actor Thanks Self. Gerd Böckmann.

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Show all 15 episodes. Thomas Schwellinger. Thomas Krass. Jonas Tjersland. Jens Ziller. Frans Vidmark. Dominik Engel. Sascha Eich.

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